A long-period fiber grating (LPG) is a one dimension (1D) periodic structure, and is formed by introducing periodic modulation of the refractive index along an optical fiber. As a band rejection filter, all light in a spectral slice is discarded without affecting the amplitude and phase of neighbouring wavelengths, with the additional advantage of low insertion losses. Long-period fiber gratings (LPFGs) functioning as band-reject filters have played a pivotal role in the realm of optical communication. The coupling from the guided mode to cladding modes is wavelength dependent so we can obtain a spectrally selective loss. It is an optical fiber. The photonic crystal fiber (PCF) is a special class of components incorporating photonic crystals with a two-dimensional (2D) periodic variation in the plane perpendicular to the fiber axis and an invariant structure along it [1-3]. Typically these fibers incorporate a number of air holes that form. Structure-Modulated Long-Period Fiber Gratings (SM-LPFGs) represent an advancement in fiber optic sensor technology, moving beyond traditional photosensitivity-based fabrication to achieve enhanced performance through the direct physical modification of the geometry of the fiber. However, loss or gain that can be controlled via optical pumping adds a new degree of freedom and – as will be shown in this chapter – brings many new and interesting properties.